27 research outputs found

    Positive Psychology: A Scholar-Practitioner Approach to Evidence Based Coaching

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    In this thesis, I assert positive psychology is the science at the heart of coaching and argue it is an evidence-based coaching model. I provide a background of positive psychology and briefly discuss its history, evolution, psychological influences and current challenges. I discuss the nature of coaching, varying definitions and common themes. Critical questions surrounding Evidence Based Practice (EBP) and how can it be applied to coaching are also addressed. Examples of single, integrative and cross-disciplinary theoretical approaches to coaching are also explored. In my final chapter, I review and answer my thesis question of whether positive psychology is an evidence based approach to coaching, including an example from a recent client engagement. Coaching considerations for using positive psychology are explored as is the future of positive psychology coaching and research areas

    Glyoxal yield from isoprene oxidation and relation to formaldehyde:chemical mechanism, constraints from SENEX aircraft observations, and interpretation of OMI satellite data

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    Glyoxal (CHOCHO) is produced in the atmosphere by oxidation of volatile organic compounds (VOCs). It is measurable from space by solar backscatter along with formaldehyde (HCHO), another oxidation product of VOCs. Isoprene emitted by vegetation is the dominant source of CHOCHO and HCHO in most of the world. We use aircraft observations of CHOCHO and HCHO from the SENEX campaign over the Southeast US in summer 2013 to better understand the time-dependent yields from isoprene oxidation, their dependences on nitrogen oxides (NOx ≡ NO + NO2), the behaviour of the CHOCHO-HCHO relationship, the quality of OMI satellite observations, and the implications for using satellite CHOCHO observations as constraints on isoprene emission. We simulate the SENEX and OMI observations with the GEOS-Chem chemical transport model featuring a new chemical mechanism for CHOCHO formation from isoprene. The mechanism includes prompt CHOCHO formation under low-NOx conditions following the isomerization of the isoprene peroxy radical (ISOPO2). The SENEX observations provide support for this prompt CHOCHO formation pathway, and are generally consistent with the GEOS-Chem mechanism. Boundary layer CHOCHO and HCHO are strongly correlated in the observations and the model, with some departure under low-NOx conditions due to prompt CHOCHO formation. SENEX vertical profiles indicate a free tropospheric CHOCHO background that is absent from the model. The OMI CHOCHO data provide some support for this free tropospheric background and show Southeast US enhancements consistent with the isoprene source but a factor of 2 too low. Part of this OMI bias is due to excessive surface reflectivities assumed in the retrieval. The OMI CHOCHO and HCHO seasonal data over the Southeast US are tightly correlated and provide redundant proxies of isoprene emission. Higher temporal resolution in future geostationary satellite observations may enable detection of the prompt CHOCHO production under low-NOx conditions apparent in the SENEX data

    The James Webb Space Telescope Mission

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    Twenty-six years ago a small committee report, building on earlier studies, expounded a compelling and poetic vision for the future of astronomy, calling for an infrared-optimized space telescope with an aperture of at least 4m4m. With the support of their governments in the US, Europe, and Canada, 20,000 people realized that vision as the 6.5m6.5m James Webb Space Telescope. A generation of astronomers will celebrate their accomplishments for the life of the mission, potentially as long as 20 years, and beyond. This report and the scientific discoveries that follow are extended thank-you notes to the 20,000 team members. The telescope is working perfectly, with much better image quality than expected. In this and accompanying papers, we give a brief history, describe the observatory, outline its objectives and current observing program, and discuss the inventions and people who made it possible. We cite detailed reports on the design and the measured performance on orbit.Comment: Accepted by PASP for the special issue on The James Webb Space Telescope Overview, 29 pages, 4 figure

    Parallax -- Text

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    Images with some text. Pages are printed front and back, hinged and folded accordion-style with a wrap-around cover. Several window cut-out

    Parallax -- Detail

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    Images with some text. Pages are printed front and back, hinged and folded accordion-style with a wrap-around cover. Several window cut-out

    Parallax -- Cover

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    Images with some text. Pages are printed front and back, hinged and folded accordion-style with a wrap-around cover. Several window cut-out

    Impaired immunity to intestinal bacterial infection in stromelysin-1 (matrix metalloproteinase-3)-deficient mice

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    Infection of mice with the intestinal bacterial pathogen Citrobacter rodentium results in colonic mucosal hyperplasia and a local Th1 inflammatory response similar to that seen in mouse models of inflammatory bowel disease. Matrix metalloproteinases (MMPs) have been shown to mediate matrix remodeling and cell migration during tissue injury and repair in the intestine. We have previously shown enhanced pathology in infected TNFRp55?/?, IL-12p40?/?, and IFN- ?/? mice, and here we show that this is associated with an increase in stromelysin-1 (MMP3) transcripts in colonic tissues. We have therefore investigated the role of MMP3 in colonic mucosal hyperplasia and the local Th1 responses using MMP3?/? mice. In MMP3?/? mice, similar mucosal thickening was observed after infection as in wild-type (WT) mice. Colonic tissues from MMP3?/? mice showed a compensatory increase in the expression of other MMP transcripts, such as MMP7 and MMP12. However, MMP3?/? mice showed delayed clearance of bacteria and delayed appearance of CD4? T lymphocytes into intestinal lamina propria. CSFE-labeled mesenteric lymph node CD4? T lymphocytes from infected WT mice migrated in fewer numbers into the mesenteric lymph nodes and colon of MMP3?/? mice than into those of WT mice. These studies show that mucosal remodeling can occur in the absence of MMP3, but that MMP3 plays a role in the migration of CD4? T lymphocytes to the intestinal mucosa

    Observing atmospheric formaldehyde (HCHO) from space: validation and intercomparison of six retrievals from four satellites (OMI, GOME2A, GOME2B, OMPS) with SEAC4RS aircraft observations over the southeast US

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    Formaldehyde (HCHO) column data from satellites are widely used as a proxy for emissions of volatile organic compounds (VOCs), but validation of the data has been extremely limited. Here we use highly accurate HCHO aircraft observations from the NASA SEAC4RS (Studies of Emissions, Atmospheric Composition, Clouds and Climate Coupling by Regional Surveys) campaign over the southeast US in August-September 2013 to validate and intercompare six retrievals of HCHO columns from four different satellite instruments (OMI, GOME2A, GOME2B and OMPS; for clarification of these and other abbreviations used in the paper, please refer to Appendix A) and three different research groups. The GEOS-Chem chemical transport model is used as a common intercomparison platform. All retrievals feature a HCHO maximum over Arkansas and Louisiana, consistent with the aircraft observations and reflecting high emissions of biogenic isoprene. The retrievals are also interconsistent in their spatial variability over the southeast US (r Combining double low line 0.4-0.8 on a 0.5° x 0.5° grid) and in their day-to-day variability (r Combining double low line 0.5-0.8). However, all retrievals are biased low in the mean by 20-51 %, which would lead to corresponding bias in estimates of isoprene emissions from the satellite data. The smallest bias is for OMI-BIRA, which has high corrected slant columns relative to the other retrievals and low scattering weights in its air mass factor (AMF) calculation. OMI-BIRA has systematic error in its assumed vertical HCHO shape profiles for the AMF calculation, and correcting this would eliminate its bias relative to the SEAC4RS data. Our results support the use of satellite HCHO data as a quantitative proxy for isoprene emission after correction of the low mean bias. There is no evident pattern in the bias, suggesting that a uniform correction factor may be applied to the data until better understanding is achieved
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